SERS and SERRS spectral studies of surface complexes

SERS and SERRS spectral studies of formation, dynamics and decomposition of transition metal-adsorbate complexes on the surface of plasmonic metal nanoparticles. SERS and SERRS spectral monitoring of free-base porphyrin metallation and acidification. Identification and exploration of surface-enhanced photochemical reactions and of plasmon-mediated processes.

 

Examples of published studies:

I. Srnová-Šloufová, B. Vlc\vková, T. L. Snoeck, D. J. Stufkens, and P. Matějka,
Surface-Enhanced Raman Scattering and Surface-Enhanced Resonance Raman Scattering Excitation Profiles of Ag-2,2`-Bipyridine Surface Complexes and of [Ru(bpy)3]2\mathpluson Ag Colloidal Surfaces: Manifestations of the Charge-Transfer Resonance Contributions to the Overall Surface Enhancement of Raman Scattering\#
Inorganic Chemistry, 39(16), 2000

DOI, BibTeX

B. Vlčková, P. Šmejkal, M. Michl, M. Procházka, P. Mojzeš, F. Lednický, and J. Pfleger,
Surface-enhanced resonance Raman spectroscopy of porphyrin and metalloporphyrin species in systems with Ag nanoparticles and their assemblies
Journal of Inorganic Biochemistry, 79(14), 2000

DOI, BibTeX

I. Šloufová, B. Vlčková, P. Mojzeš, I. Matulková, I. Císařová, M. Procházka, and J. Vohlídal,
Probing the Formation, Structure, and Reactivity of Zn(II), Ag(I), and Fe(II) Complexes with 2,2\prime:6\prime,2\dprime-Terpyridine on Ag Nanoparticles Surfaces by Time Evolution of SERS Spectra, Factor Analysis, and DFT Calculations
The Journal of Physical Chemistry C, 122(11), 2018

DOI, BibTeX